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Darmstadtium-281


Darmstadtium (Ds) is a synthetic element, and thus a standard atomic mass cannot be given. Like all synthetic elements, it has no stable isotopes. The first isotope to be synthesized was 269Ds in 1994. There are 7 or 8 known radioisotopes from 267Ds (or 269Ds) to 281Ds (with many gaps) and 2 or 3 known isomers. The longest-lived isotope is 281Ds with a half-life of 9.6 seconds.

Super-heavy elements such as darmstadtium are produced by bombarding lighter elements in particle accelerators that induce fusion reactions. Whereas most of the isotopes of darmstadtium can be synthesized directly this way, some heavier ones have only been observed as decay products of elements with higher atomic numbers.

Depending on the energies involved, the former are separated into "hot" and "cold". In hot fusion reactions, very light, high-energy projectiles are accelerated toward very heavy targets (actinides), giving rise to compound nuclei at high excitation energy (~40–50 MeV) that may either fission or evaporate several (3 to 5) neutrons. In cold fusion reactions, the produced fused nuclei have a relatively low excitation energy (~10–20 MeV), which decreases the probability that these products will undergo fission reactions. As the fused nuclei cool to the ground state, they require emission of only one or two neutrons, and thus, allows for the generation of more neutron-rich products. The latter is a distinct concept from that of where nuclear fusion claimed to be achieved at room temperature conditions (see cold fusion).

Before the first successful synthesis of darmstadtium in 1994 by the GSI team, scientists at GSI also tried to synthesize darmstadtium by bombarding lead-208 with nickel-64 in 1986. No darmstadtium atoms were identified. After an upgrade of their facilities, the team at GSI successfully detected 9 atoms of 271Ds in two runs of their discovery experiment in 1994. This reaction was successfully repeated in 2000 by GSI (4 atoms), in 2000 and 2004 by the Lawrence Berkeley National Laboratory (LBNL) (9 atoms in total) and in 2002 by RIKEN (14 atoms). The GSI team studied the analogous reaction with nickel-62 instead of nickel-64 in 1994 as part of their discovery experiment. Three atoms of 269Ds were detected. A fourth decay chain was measured but was subsequently retracted.


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