Cupellation

Cupellation is a refining process in metallurgy, where ores or alloyed metals are treated under very high temperatures and have controlled operations to separate noble metals, like gold and silver, from base metals like lead, copper, zinc, arsenic, antimony or bismuth, present in the ore. The process is based on the principle that precious metals do not oxidise or react chemically, unlike the base metals; so when they are heated at high temperatures, the precious metals remain apart and the others react forming slags or other compounds.

Since the Early Bronze Age, the process was used to obtain silver from smelted lead ores. By the Middle Ages and the Renaissance, cupellation was one of the most common processes for refining precious metals. By then, fire assays were used for assaying minerals, that is, testing fresh metals such as lead and recycled metals to know their purity for jewellery and coin making. Cupellation is still in use today.

Native silver is a rare element, although it exists as such. It is usually found in nature combined with other metals, or in minerals that contain silver compounds, generally in the form of sulfides such as galena (lead sulfide) or cerussite (lead carbonate). So the primary production of silver requires the smelting and then cupellation of argentiferous lead ores.

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