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Chromic oxide

Chromium(III) oxide
Cr2o3 gruener farbstoff.jpg
Corundum struct.png
Names
Other names
Chromium sesquioxide
Chromia
Chrome green
Eskolaite
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
ECHA InfoCard 100.013.783
PubChem CID
RTECS number GB6475000
UNII
Properties
Cr2O3
Molar mass 151.9904 g/mol
Appearance light to dark green, fine crystals
Density 5.22 g/cm3
Melting point 2,435 °C (4,415 °F; 2,708 K)
Boiling point 4,000 °C (7,230 °F; 4,270 K)
insoluble
Solubility in alcohol insoluble in alcohol, acetone, acids
+1960.0·10−6 cm3/mol
2.551
Structure
hexagonal
Thermochemistry
81 J·mol−1·K−1
−1128 kJ·mol−1
Hazards
US health exposure limits (NIOSH):
PEL (Permissible)
TWA 1 mg/m3
REL (Recommended)
TWA 0.5 mg/m3
IDLH (Immediate danger)
250 mg/m3
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
YesY  (what is YesYN ?)
Infobox references

Chromium(III) oxide is the inorganic compound of the formula Cr
2
O
3
. It is one of the principal oxides of chromium and is used as a pigment. In nature, it occurs as the rare mineral eskolaite.

Cr
2
O
3
adopts the corundum structure, consisting of a hexagonal close packed array of oxide anions with ⅔ of the octahedral holes occupied by chromium. Similar to corundum, Cr
2
O
3
is a hard, brittle material (Mohs hardness 8 to 8.5). It is antiferromagnetic up to 307 K, the Néel temperature. It is not readily attacked by acids.

Cr
2
O
3
occurs naturally in mineral eskolaite, which is found in chromium-rich tremolite skarns, metaquartzites, and chlorite veins. Eskolaite is also a rare component of chondrite meteorites. The mineral is named after Finnish geologist Pentti Eskola.


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