Charcoal is a lightweight, black residue, consisting of carbon and any remaining ash, obtained by removing water and other volatile constituents from animal and vegetation substances. Charcoal is usually produced by slow pyrolysis — the heating of wood or other substances in the absence of oxygen (see char and biochar).
Historically, the production of wood charcoal in locations where there is an abundance of wood dates back to a very ancient period, and generally consists of piling of wood on their ends so as to form a conical pile, openings being left at the bottom to admit air, with a central shaft to serve as a flue. The whole pile is covered with turf or moistened clay. The firing is begun at the bottom of the flue, and gradually spreads outwards and upwards. The success of the operation depends upon the rate of the combustion. Under average conditions, 100 parts of wood yield about 60 parts by volume, or 25 parts by weight, of charcoal; small-scale production on the spot often yields only about 50%, while large-scale became efficient to about 90% even by the seventeenth century. The operation is so delicate that it was generally left to colliers (professional charcoal burners). They often lived alone in small huts in order to tend their wood piles. For example, in the Harz Mountains of Germany, charcoal burners lived in conical huts called Köten which are still much in evidence today.
The massive production of charcoal (at its height employing hundreds of thousands, mainly in Alpine and neighbouring forests) was a major cause of deforestation, especially in Central Europe. In England, many woods were managed as coppices, which were cut and regrown cyclically, so that a steady supply of charcoal would be available (in principle) forever; complaints (as early as the Stuart period) about shortages may relate to the results of temporary over-exploitation or the impossibility of increasing production to match growing demand. The increasing scarcity of easily harvested wood was a major factor behind the switch to fossil fuel equivalents, mainly coal and brown coal for industrial use.