Calorific Value

The calorific value is the total energy released as heat when a substance undergoes complete combustion with oxygen under standard conditions. The chemical reaction is typically a hydrocarbon or other organic molecule reacting with oxygen to form carbon dioxide and water and release heat. It may be expressed with the quantities:

The calorific value is conventionally measured with a bomb calorimeter. It may also be calculated as the difference between the heat of formation ΔHo
f of the products and reactants (though this approach is purely empirical since most heats of formation are calculated from measured heats of combustion). For a fuel of composition C_cH_hO_oN_n, the magnitude of the heat of combustion is 418 kJ/mol (c + 0.3 h – 0.5 o) to a good approximation (±3%). The calorific value of all organic compounds has the sign corresponding to an exothermic reaction (negative in the standard chemical convention) because the double bond in molecular oxygen is much weaker than other double bonds or pairs of single bonds, particularly those in the combustion products carbon dioxide and water; conversion of the weak bonds in O₂ to the stronger bonds in CO₂ and H₂O releases energy as heat.

The heating value (or energy value or calorific value) of a substance, usually a fuel or food (see food energy), is the amount of heat released during the combustion of a specified amount of it. The energy value is a characteristic for each substance. It is measured in units of energy per unit of the substance, usually mass, such as: kJ/kg, kJ/mol, kcal/kg, Btu/lb. Heating value is commonly determined by use of a bomb calorimeter.

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