In fluid dynamics, the baroclinity (sometimes called baroclinicity) of a stratified fluid is a measure of how misaligned the gradient of pressure is from the gradient of density in a fluid. In meteorology a baroclinic atmosphere is one for which the density depends on both the temperature and the pressure; contrast this with a barotropic atmosphere, for which the density depends only on the pressure. In atmospheric terms, the barotropic zones of the Earth are generally found in the central latitudes, or tropics, whereas the baroclinic areas are generally found in the mid-latitude/polar regions.
Baroclinity is proportional to
which is proportional to the sine of the angle between surfaces of constant pressure and surfaces of constant density. Thus, in a barotropic fluid (which is defined by zero baroclinity), these surfaces are parallel.
Areas of high atmospheric baroclinity are characterized by the frequent formation of cyclones.
Baroclinic instability is a fluid dynamical instability of fundamental importance in the atmosphere and in the oceans. In the atmosphere it is the dominant mechanism shaping the cyclones and anticyclones that dominate weather in mid-latitudes. In the ocean it generates a field of mesoscale (100 km or smaller) eddies that play various roles in oceanic dynamics and the transport of tracers. Baroclinic instability is a concept relevant to rapidly rotating, strongly stratified fluids.
Whether a fluid counts as rapidly rotating is determined in this context by the Rossby number, which is a measure of how close the flow is to solid body rotation. More precisely, a flow in solid body rotation has vorticity that is proportional to its angular velocity. The Rossby number is a measure of the departure of the vorticity from that of solid body rotation. The Rossby number must be small for the concept of baroclinic instability to be relevant. When the Rossby number is large, other kinds of instabilities, often referred to as inertial, become more relevant.