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Aluminian Hisingerite

Hisingerite
Hisingerite-282352.jpg
Crystallized plates of reddish-brown, silver metallic-lustre hisingerite crystals
General
Category Silicate mineral
Formula
(repeating unit)
Fe3+2Si2O5(OH)4·2H2O
Strunz classification 9.ED.10
Crystal system Monoclinic
Unknown space group
Unit cell a = 5.4, b = 9.03
c = 14.99 [Å]; β = 98.32°; Z = 4
Identification
Color Black, brownish-black
Crystal habit Massive, compact; acicular, may be minutely spherical.
Cleavage None
Fracture Conchoidal
Tenacity Brittle
Mohs scale hardness 2.5 - 3.0
Luster Vitreous, resinous, greasy
Streak Yellowish brown, green
Diaphaneity Transparent to translucent
Specific gravity 2.43 - 2.67
Optical properties Biaxial (-)
Refractive index nα = 1.715 nγ = 1.730
Birefringence δ = 0.015
References

Hisingerite is an iron(III) phyllosilicate mineral with formula Fe3+2Si2O5(OH)4·2H2O. A black or dark brown, lustrous secondary mineral, it is formed by the weathering or hydrothermal alteration of other iron silicate and sulfide minerals.

It was first described in 1828 for an occurrence in Riddarhyttan, Vastmanland, Sweden. It was named after Wilhelm Hisinger (1766–1852), a Swedish chemist.

There are also aluminian hisingerite variety in which one of the iron atoms is replaced by aluminium and chrome-alumina-hisingerite variety in which chromium substitutes for iron.


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