*** Welcome to piglix ***

3-Hydroxybutanone

Acetoin
3-Hydroxybutanone
Names
Other names
3-Hydroxybutanone
Acetyl methyl carbinol
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
ECHA InfoCard 100.007.432
EC Number 208-174-1
KEGG
PubChem CID
RTECS number EL8790000
UNII
Properties
C4H8O2
Molar mass 88.11 g·mol−1
Appearance slightly yellow liquid or crystals
Odor bland, yogurt-like
Density 1.012 g/cm3
Melting point 15 °C (59 °F; 288 K)
Boiling point 148 °C (298 °F; 421 K)
1000 g/l (20 °C)
Solubility in other solvents Soluble in alcohol
Slightly soluble in ether, petroleum ether
Miscible in propylene glycol
Insoluble in vegetable oil
log P -0.36
Acidity (pKa) 13.72
-39.4
1.4171
Hazards
Safety data sheet MSDS
Flash point 41 °C (106 °F; 314 K)
Lethal dose or concentration (LD, LC):
LD50 (median dose)
> 5000 mg/kg (rat, oral)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N  (what is YesYN ?)
Infobox references

Acetoin, also known as 3-hydroxybutanone or acetyl methyl carbinol, with the molecular formula is C4H8O2, is a colorless or pale yellow to green yellow liquid with a pleasant, buttery odor. Acetoin is a chiral molecule. The form produced by bacteria is (R)-acetoin.

Acetoin is a neutral, four-carbon molecule used as an external energy store by a number of fermentive bacteria. It is produced by the decarboxylation of alpha-acetolactate, a common precursor in the biosynthesis of branched-chain amino acids. Owing to its neutral nature, production and excretion of acetoin during exponential growth prevents overacidification of the cytoplasm and the surrounding medium that would result from accumulation of acidic metabolic products, such as acetic acid and citric acid. Once superior carbon sources are exhausted, and the culture enters stationary phase, acetoin can be used to maintain the culture density. The conversion of acetoin into acetyl-CoA is catalysed by the acetoin dehydrogenase complex, following a mechanism largely analogous to the pyruvate dehydrogenase complex; however, as acetoin is not a 2-oxoacid, it does not undergo decarboxylation by the E1 enzyme; instead, a molecule of acetaldehyde is released. In some bacteria, acetoin can also be reduced to 2,3-butanediol by acetoin reductase/2,3-butanediol dehydrogenase.

The Voges-Proskauer test is a commonly used microbiological test for acetoin production.

Acetoin, along with diacetyl, is one of the compounds giving butter its characteristic flavor. Because of this, manufacturers of partially hydrogenated oils typically add artificial butter flavor - acetoin and diacetyl - (along with beta carotene for the yellow color) to the final product, which would otherwise be tasteless.


...
Wikipedia

...