"When I Think About Angels" is a song co-written and recorded by Australian country music artist Jamie O'Neal. It was released in March 2001 as the second single from O'Neal's Shiver album. The song reached Number One on the Billboard Hot Country Singles & Tracks (now Hot Country Songs) charts. It also peaked at #35 on the U.S. Billboard Hot 100. The song was written by O'Neal, Roxie Dean and Sonny Tillis.

The song is a mid-tempo in which the narrator confesses that everything reminds her of her significant other.

The music video was directed by Trey Fanjoy and premiered in mid-2001.

"When I Think About Angels" debuted at number 45 on the U.S. Billboard Hot Country Singles & Tracks for the chart week of March 31, 2001. Having peaked at number 1 on the chart dated for August 4, 2001, O'Neal became the first female country singer to send her first two singles to number 1 since Deana Carter did so in 1996–1997.

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