Volcanic ash

Volcanic ash consists of fragments of pulverized rock, minerals and volcanic glass, created during volcanic eruptions and measuring less than 2 mm (0.079 inches) in diameter. The term volcanic ash is also often loosely used to refer to all explosive eruption products (correctly referred to as tephra), including particles larger than 2mm. Volcanic ash is formed during explosive volcanic eruptions when dissolved gases in magma expand and escape violently into the atmosphere. The force of the escaping gas shatters the magma and propels it into the atmosphere where it solidifies into fragments of volcanic rock and glass. Ash is also produced when magma comes into contact with water during phreatomagmatic eruptions, causing the water to explosively flash to steam leading to shattering of magma. Once in the air, ash is transported by wind up to thousands of kilometers away.

Due to its wide dispersal, ash can have a number of impacts on society, including human and animal health, disruption to aviation, disruption to critical infrastructure (e.g., electric power supply systems, telecommunications, water and waste-water networks, transportation), primary industries (e.g., agriculture), buildings and structures.

Volcanic ash is formed during explosive volcanic eruptions, phreatomagmatic eruptions and during transport in pyroclastic density currents.

Explosive eruptions occur when magma decompresses as it rises, allowing dissolved volatiles (dominantly water and carbon dioxide) to exsolve into gas bubbles. As more bubbles nucleate a foam is produced, which decreases the density of the magma, accelerating it up the conduit. Fragmentation occurs when bubbles occupy ~70-80 vol% of the erupting mixture. When fragmentation occurs, violently expanding bubbles tear the magma apart into fragments which are ejected into the atmosphere where they solidify into ash particles. Fragmentation is a very efficient process of ash formation and is capable of generating very fine ash even without the addition of water.

Volcanic ash is also produced during phreatomagmatic eruptions. During these eruptions fragmentation occurs when magma comes into contact with bodies of water (such as the sea, lakes and marshes) groundwater, snow or ice. As the magma, which is significantly hotter than the boiling point of water, comes into contact with water an insulating vapor film forms (Leidenfrost effect). Eventually this vapor film will collapse leading to direct coupling of the cold water and hot magma. This increases the heat transfer which leads to the rapid expansion of water and fragmentation of the magma into small particles which are subsequently ejected from the volcanic vent. Fragmentation causes an increase in contact area between magma and water creating a feedback mechanism, leading to further fragmentation and production of fine ash particles.

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