Triboluminescent

Triboluminescence is an optical phenomenon in which light is generated through the breaking of chemical bonds in a material when it is pulled apart, ripped, scratched, crushed, or rubbed (see tribology). The phenomenon is not fully understood, but appears to be caused by the separation and reunification of electrical charges. The term comes from the Greek ("to rub"; see tribology) and the Latin lumen (light). Triboluminescence can be observed when breaking sugar crystals and peeling adhesive tapes.

Triboluminescence is often used as a synonym for fractoluminescence (a term sometimes used when referring only to light emitted from fractured crystals). Triboluminescence differs from piezoluminescence in that a piezoluminescent material emits light when it is deformed, as opposed to broken. These are examples of mechanoluminescence, which is luminescence resulting from any mechanical action on a solid.

The Uncompahgre Ute Indians from Central Colorado are one of the first documented groups of people in the world credited with the application of mechanoluminescence involving the use of quartz crystals to generate light. The Ute constructed special ceremonial rattles made from buffalo rawhide which they filled with clear quartz crystals collected from the mountains of Colorado and Utah. When the rattles were shaken at night during ceremonies, the friction and mechanical stress of the quartz crystals impacting together produced flashes of light visible through the translucent buffalo hide.

The first recorded observation is attributed to English scholar Francis Bacon when he recorded in his 1620 Novum Organum that "It is well known that all sugar, whether candied or plain, if it be hard, will sparkle when broken or scraped in the dark." The scientist Robert Boyle also reported on some of his work on triboluminescence in 1663. In the late 1790s, sugar production began to produce more refined sugar crystals. These crystals were formed into a large solid cone for transport and sale. This solid cone of sugar had to be broken into usable chunks using a device known as sugar nips. People began to notice that as sugar was "nipped" in low light, tiny bursts of light were visible.

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