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Sulfuric acid

Sulfuric acid
Sulfuric-acid-Givan-et-al-1999-3D-vdW.png
Space-filling model
Sulfuric-acid-Givan-et-al-1999-3D-balls.png
Ball-and-stick model
S=O bond length = 142.2 pm, S-O bond length = 157.4 pm, O-H bond length = 97 pm
Sulphuric acid 96 percent extra pure.jpg
Names
IUPAC name
Sulfuric acid
Other names
Oil of vitriol, hydrogen sulfate
Identifiers
7664-93-9 YesY
3D model (Jmol) Interactive image
ChEBI CHEBI:26836 YesY
ChEMBL ChEMBL572964 YesY
ChemSpider 1086 YesY
ECHA InfoCard 100.028.763
EC Number 231-639-5
E number E513 (acidity regulators, ...)
2122
KEGG D05963 YesY
PubChem 1118
RTECS number WS5600000
UNII O40UQP6WCF YesY
UN number 1830
Properties
H
2
SO
4
Molar mass 98.079 g/mol
Appearance Clear, colorless liquid
Odor odorless
Density 1.84 g/cm3, liquid
Melting point 10 °C (50 °F; 283 K)
Boiling point 337 °C (639 °F; 610 K) When sulfuric acid is above 300 °C (572 °F), it will decompose slowly
miscible
Vapor pressure 0.001 mmHg (20 °C)
Acidity (pKa) −3, 1.99
Viscosity 26.7 cP (20 °C)
Thermochemistry
157 J·mol−1·K−1
−814 kJ·mol−1
Hazards
Safety data sheet External MSDS
GHS pictograms The corrosion pictogram in the Globally Harmonized System of Classification and Labelling of Chemicals (GHS)
GHS signal word Danger
H314
P260, P264, P280, P301+330+331, P303+361+353, P363, P304+340, P305+351+338, P310, P321, P310, P405, P501
Corrosive C
R-phrases R35
S-phrases (S1/2) S26 S30 S45
NFPA 704
Flammability code 0: Will not burn. E.g., water Health code 3: Short exposure could cause serious temporary or residual injury. E.g., chlorine gas Reactivity code 2: Undergoes violent chemical change at elevated temperatures and pressures, reacts violently with water, or may form explosive mixtures with water. E.g., phosphorus Special hazard W: Reacts with water in an unusual or dangerous manner. E.g., cesium, sodiumNFPA 704 four-colored diamond
Flash point Non-flammable
15 mg/m3 (IDLH), 1 mg/m3 (TWA), 2 mg/m3 (STEL)
Lethal dose or concentration (LD, LC):
LD50 (median dose)
2140 mg/kg (rat, oral)
50 mg/m3 (guinea pig, 8 hr)
510 mg/m3 (rat, 2 hr)
320 mg/m3 (mouse, 2 hr)
18 mg/m3 (guinea pig)
87 mg/m3 (guinea pig, 2.75 hr)
US health exposure limits (NIOSH):
PEL (Permissible)
TWA 1 mg/m3
REL (Recommended)
TWA 1 mg/m3
IDLH (Immediate danger)
15 mg/m3
Related compounds
Related strong acids
Selenic acid
Hydrochloric acid
Nitric acid
Chromic acid
Related compounds
Sulfurous acid
Peroxymonosulfuric acid
Sulfur trioxide
Oleum
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N  (what is YesYN ?)
Infobox references

Sulfuric acid (alternative spelling sulphuric acid) is a highly corrosive strong mineral acid with the molecular formula H2SO4 and molecular weight 98.079 g/mol. It is a pungent-ethereal, colorless to slightly yellow viscous liquid that is soluble in water at all concentrations. Sometimes, it is dyed dark brown during production to alert people to its hazards. The historical name of this acid is oil of vitriol.

Sulfuric acid is a diprotic acid and shows different properties depending upon its concentration. Its corrosiveness on other materials, like metals, living tissues or even stones, can be mainly ascribed to its strong acidic nature and, if concentrated, strong dehydrating and oxidizing properties. Sulfuric acid at a high concentration can cause very serious damage upon contact, since not only does it cause chemical burns via hydrolysis, but also secondary thermal burns through dehydration. It can lead to permanent blindness if splashed onto eyes and irreversible damage if swallowed. Moreover, it is hygroscopic, readily absorbing water vapour from the air.


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