Sulfur difluoride
|
|||
 |
|||
| Names | |||
|---|---|---|---|
|
IUPAC name
sulfoxylic difluoride
|
|||
| Identifiers | |||
|
3D model (JSmol)
|
|||
| ChemSpider | |||
|
PubChem CID
|
|||
|
|||
|
|||
| Properties | |||
| SF2 | |||
| Molar mass | 70.062 g/mol | ||
|
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
|
|||
| Infobox references | |||
Sulfur difluoride is an inorganic compound with the chemical formula SF2. It can be generated by the reaction of sulfur dichloride and potassium fluoride or mercury(II) fluoride at low pressures:
The F−S−F bond angle is 98°, and the length of S−F bond is 159 pm. The compound is highly unstable, decomposing to FSSF3. This unsymmetrical isomer of S2F4 is proposed to arise via insertion of SF2 into the S−F bond of a second molecule SF2:
It can also be formed from oxygen difluoride and hydrogen sulfide:
...
Wikipedia