Stratospheric
The stratosphere (/ˈstrætəˌsfɪər, -toʊ-/) is the second major layer of Earth's atmosphere, just above the troposphere, and below the mesosphere. About 20% of the atmosphere's mass is contained in the stratosphere. The stratosphere is stratified in temperature, with warmer layers higher and cooler layers closer to the Earth. The increase of temperature with altitude is a result of the absorption of the Sun's ultraviolet radiation by the ozone. This is in contrast to the troposphere, near the Earth's surface, where temperatures decreases with altitude. The border between the troposphere and stratosphere, the tropopause, marks where this temperature inversion begins. Near the equator, the stratosphere starts at 18 km (59,000 ft; 11 mi); at mid latitudes, it starts at 10–13 km (33,000–43,000 ft; 6.2–8.1 mi) and ends at 50 km (160,000 ft; 31 mi); at the poles, it starts at about 8 km (26,000 ft; 5.0 mi). Temperatures vary within the stratosphere with the seasons, in particular with the polar night (winter). The greatest variation of temperature takes place over the poles in the lower stratosphere; those variations are largely steady at lower latitudes and higher altitudes.
The mechanism describing the formation of the ozone layer was described by British mathematician Sydney Chapman in 1930. Molecular oxygen absorbs high energy sunlight in the UV-C region, at wavelengths shorter than about 240 nm. The oxygen atoms produced combine with molecular oxygen to form ozone. Ozone in turn is photolysed much more rapidly than molecular oxygen as it has a stronger absorption that occurs at longer wavelengths, where the solar emission is more intense. Ozone (O3) photolysis produces O and O2. The oxygen atom product combines with atmospheric molecular oxygen to reform O3, releasing heat. The rapid photolysis and reformation of ozone heats the stratosphere resulting in a temperature inversion. This increase of temperature with altitude is characteristic of the stratosphere; its resistance to vertical mixing means that it is stratified. Within the stratosphere temperatures increase with altitude (see temperature inversion); the top of the stratosphere has a temperature of about 270 K (−3°C or 26.6°F). This vertical stratification, with warmer layers above and cooler layers below, makes the stratosphere dynamically stable: there is no regular convection and associated turbulence in this part of the atmosphere. However, exceptionally energetic convection processes, such as volcanic eruption columns and overshooting tops in severe supercell thunderstorms, may carry convection into the stratosphere on a very local and temporary basis. Overall the attenuation of solar UV at wavelengths that damage DNA by the ozone layer allows life to exist on the surface of the planet outside of the ocean. All air entering the stratosphere must pass through the tropopause, the temperature minimum that divides the troposphere and stratosphere. The rising air is literally freeze dried; the stratosphere is a very dry place. The top of the stratosphere is called the stratopause, above which the temperature decreases with height.
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