The Rankine cycle is a model that is used to predict the performance of steam turbine systems, though the theoretical principle also applies to reciprocating engines such as steam locomotives. The Rankine cycle is an idealized thermodynamic cycle of a heat engine that converts heat into mechanical work while undergoing phase change. The heat is supplied externally to a closed loop, which usually uses water as the working fluid. It is named after William John Macquorn Rankine, a Scottish polymath and Glasgow University professor.
The Rankine cycle closely describes the process by which steam-operated heat engines commonly found in thermal power generation plants generate power. The heat sources used in these power plants are usually nuclear fission or the combustion of fossil fuels such as coal, natural gas, and oil.
The efficiency of the Rankine cycle is limited by the high heat of vaporization of the working fluid. Also, unless the pressure and temperature reach super critical levels in the steam boiler, the temperature range the cycle can operate over is quite small: steam turbine entry temperatures are typically around 565 °C and steam condenser temperatures are around 30 °C. This gives a theoretical maximum Carnot efficiency for the steam turbine alone of about 63.8% compared with an actual overall thermal efficiency of up to 42% for a modern coal-fired power station. This low steam turbine entry temperature (compared to a gas turbine) is why the Rankine (steam) cycle is often used as a bottoming cycle to recover otherwise rejected heat in combined-cycle gas turbine power stations.
The working fluid in a Rankine cycle follows a closed loop and is reused constantly. The water vapor with condensed droplets often seen billowing from power stations is created by the cooling systems (not directly from the closed-loop Rankine power cycle) and represents the means for (low temperature) waste heat to exit the system, allowing for the addition of (higher temperature) heat that can then be converted to useful work (power). This 'exhaust' heat is represented by the "Qout" flowing out of the lower side of the cycle shown in the T/s diagram below. Cooling towers operate as large heat exchangers by absorbing the latent heat of vaporization of the working fluid and simultaneously evaporating cooling water to the atmosphere. While many substances could be used as the working fluid in the Rankine cycle, water is usually the fluid of choice due to its favorable properties, such as its non-toxic and unreactive chemistry, abundance, and low cost, as well as its thermodynamic properties. By condensing the working steam vapor to a liquid the pressure at the turbine outlet is lowered and the energy required by the feed pump consumes only 1% to 3% of the turbine output power and these factors contribute to a higher efficiency for the cycle. The benefit of this is offset by the low temperatures of steam admitted to the turbine(s). Gas turbines, for instance, have turbine entry temperatures approaching 1500°C. However, the thermal efficiency of actual large steam power stations and large modern gas turbine stations are similar.