Vinegar is a liquid consisting of about 5–20% acetic acid (CH3COOH), water (H2O), and trace chemicals that may include flavorings. Acetic acid is produced by the fermentation of ethanol by acetic acid bacteria. Vinegar is now mainly used as a cooking ingredient, or in pickling. There are many types of vinegar, depending upon the source materials.
As the most easily manufactured mild acid, it has historically had a wide variety of industrial, medical, and domestic uses. Some of these are still commonly practiced, such as its use as a household cleaner.
Commercial vinegar is produced either by a fast or a slow fermentation process. In general, slow methods are used in traditional vinegars, where fermentation proceeds over the course of a few months to a year. The longer fermentation period allows for the accumulation of a nontoxic slime composed of acetic acid bacteria.
Fast methods add mother of vinegar (a bacterial culture) to the source liquid before adding air to oxygenate and promote the fastest fermentation. In fast production processes, vinegar may be produced in 20 hours up to three days.
The conversion of ethanol (CH3CH2OH) and oxygen (O2) to acetic acid (CH3COOH) takes place by the following reaction:
Vinegar contains numerous flavonoids, phenolic acids, and aldehydes, which vary in content depending on the source material used to make the vinegar, such as orange peel or various fruit juice concentrates.
The word vinegar arrived in Middle English from Old French vyn egre, which in turn derives from Latin vinum (wine) + acer (sour).