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Sodium metal

Sodium,  11Na
Na (Sodium).jpg
General properties
Appearance silvery white metallic
Standard atomic weight (Ar, standard) 22.98976928(2)
Sodium in the periodic table
Hydrogen Helium
Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon
Sodium Magnesium Aluminium Silicon Phosphorus Sulfur Chlorine Argon
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
Caesium Barium Lanthanum Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury (element) Thallium Lead Bismuth Polonium Astatine Radon
Francium Radium Actinium Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Roentgenium Copernicium Nihonium Flerovium Moscovium Livermorium Tennessine Oganesson
Li

Na

K
neonsodiummagnesium
Atomic number (Z) 11
Group group 1 (alkali metals)
Period period 3
Element category   alkali metal
Block s-block
Electron configuration [Ne] 3s1
Electrons per shell
2, 8, 1
Physical properties
Phase (at STP) solid
Melting point 370.944 K ​(97.794 °C, ​208.029 °F)
Boiling point 1156.090 K ​(882.940 °C, ​1621.292 °F)
Density (near r.t.) 0.968 g/cm3
when liquid (at m.p.) 0.927 g/cm3
Critical point 2573 K, 35 MPa (extrapolated)
Heat of fusion 2.60 kJ/mol
Heat of vaporization 97.42 kJ/mol
Molar heat capacity 28.230 J/(mol·K)
Vapor pressure
P (Pa) 1 10 100 1 k 10 k 100 k
at T (K) 554 617 697 802 946 1153
Atomic properties
Oxidation states +1, −1 ​(a strongly basic oxide)
Electronegativity Pauling scale: 0.93
Ionization energies
  • 1st: 495.8 kJ/mol
  • 2nd: 4562 kJ/mol
  • 3rd: 6910.3 kJ/mol
  • (more)
Atomic radius empirical: 186 pm
Covalent radius 166±9 pm
Van der Waals radius 227 pm
Color lines in a spectral range
Miscellanea
Crystal structure body-centered cubic (bcc)
Body-centered cubic crystal structure for sodium
Speed of sound thin rod 3200 m/s (at 20 °C)
Thermal expansion 71 µm/(m·K) (at 25 °C)
Thermal conductivity 142 W/(m·K)
Electrical resistivity 47.7 nΩ·m (at 20 °C)
Magnetic ordering paramagnetic
Magnetic susceptibility +16.0·10−6 cm3/mol (298 K)
Young's modulus 10 GPa
Shear modulus 3.3 GPa
Bulk modulus 6.3 GPa
Mohs hardness 0.5
Brinell hardness 0.69 MPa
CAS Number 7440-23-5
History
Discovery and first isolation Humphry Davy (1807)
Main isotopes of sodium
Iso­tope Abun­dance Half-life (t1/2) Decay mode Pro­duct
22Na trace 2.602 y β+ 22Ne
23Na 100% stable
24Na trace 14.96 h β 24Mg
| references |
NFPA 704
fire diamond
Flammability code 1: Must be pre-heated before ignition can occur. Flash point over 93 °C (200 °F). E.g., canola oil Health code 3: Short exposure could cause serious temporary or residual injury. E.g., chlorine gas Reactivity code 2: Undergoes violent chemical change at elevated temperatures and pressures, reacts violently with water, or may form explosive mixtures with water. E.g., phosphorus Special hazard W: Reacts with water in an unusual or dangerous manner. E.g., cesium, sodiumNFPA 704 four-colored diamond
The fire diamond hazard sign for sodium metal

Sodium is a chemical element with symbol Na (from Latin natrium) and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 of the periodic table, because it has a single electron in its outer shell that it readily donates, creating a positively charged ion—the Na+cation. Its only stable isotope is 23Na. The free metal does not occur in nature, but must be prepared from compounds. Sodium is the sixth most abundant element in the Earth's crust, and exists in numerous minerals such as feldspars, sodalite, and rock salt (NaCl). Many salts of sodium are highly water-soluble: sodium ions have been leached by the action of water from the Earth's minerals over eons, and thus sodium and chlorine are the most common dissolved elements by weight in the oceans.

Sodium was first isolated by Humphry Davy in 1807 by the electrolysis of sodium hydroxide. Among many other useful sodium compounds, sodium hydroxide (lye) is used in soap manufacture, and sodium chloride (edible salt) is a de-icing agent and a nutrient for animals including humans.

Sodium is an essential element for all animals and some plants. Sodium ions are the major cation in the extracellular fluid (ECF) and as such are the major contributor to the ECF osmotic pressure and ECF compartment volume. Loss of water from the ECF compartment increases the sodium concentration, a condition called hypernatremia. Isotonic loss of water and sodium from the ECF compartment decreases the size of that compartment in a condition called ECF hypovolemia.


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