Smoluchowski coagulation equation
In statistical physics, the Smoluchowski coagulation equation is a population balance equation introduced by Marian Smoluchowski in a seminal 1916 publication, describing the time evolution of the number density of particles as they coagulate (in this context "clumping together") to size x at time t.
Simultaneous coagulation (or aggregation) is encountered in processes involving polymerization,coalescence of aerosols,emulsication,flocculation.
The distribution of particle size change in time according to the interrelation of all particles of the system. Therefore, the Smoluchowski coagulation equation is an integrodifferential equation of the particle-size distribution. In the case when the sizes of the coagulated particles are continuous variables, the equation involves an integral:
If dy is interpreted as a discrete measure, i.e. when particles join in discrete sizes, then the discrete form of the equation is a summation:
There exist a unique solution for a chosen kernel function.
The operator, K, is known as the coagulation kernel and describes the rate at which particles of size coagulate with particles of size . Analytic solutions to the equation exist when the kernel takes one of three simple forms:
...
Wikipedia