The semiconductor luminescence equations (SLEs) describe luminescence of semiconductors resulting from spontaneous recombination of electronic excitations, producing a flux of spontaneously emitted light. This description established the first step toward semiconductor quantum optics because the SLEs simultaneously includes the quantized light–matter interaction and the Coulomb-interaction coupling among electronic excitations within a semiconductor. The SLEs are one of the most accurate methods to describe light emission in semiconductors and they are suited for a systematic modeling of semiconductor emission ranging from excitonic luminescence to lasing.
Due to randomness of the vacuum-field fluctuations, semiconductor luminescence is incoherent whereas the extensions of the SLEs include the possibility to study resonance fluorescence resulting from optical pumping with coherent laser light. At this level, one is often interested to control and access higher-order photon-correlation effects, distinct many-body states, as well as light–semiconductor entanglement. Such investigations are the basis of realizing and developing the field of quantum-optical spectroscopy which is a branch of quantum optics.
The derivation of the SLEs starts from a system Hamiltonian that fully includes many-body interactions, quantized light field, and quantized light–matter interaction. Like almost always in many-body physics, it is most convenient to apply the second-quantization formalism. For example, a light field corresponding to frequency is then described through Boson creation and annihilation operators and , respectively, where the "hat" over signifies the operator nature of the quantity. The operator-combination determines the photon-number operator.