Resin casting is a method of plastic casting where a mold is filled with a liquid synthetic resin, which then hardens. It is primarily used for small-scale production like industrial prototypes and dentistry. It can be done by amateur hobbyists with little initial investment, and is used in the production of collectible toys, models and figures, as well as small-scale jewelry production.
The synthetic resin for such processes is a monomer for making a plastic thermosetting polymer. During the setting process, the liquid monomer polymerizes into the polymer, thereby hardening into a solid.
Single-monomer resins may be used in the process, which form homopolymers (polymers containing only one type of polymer). In such uses, the "curing agent" mixed with the resin contains what is loosely referred to as a "catalyst," but which is more technically an initial source of free radicals (such as MEKP) to act as an initiator in a free-radical chemical chain reaction polymerization. Alternately, resin casting may be accomplished with a resin plus a nearly equal amount of a "hardener" liquid (as in many epoxy resin or polyester resin systems), which functionally contains a second polymer, for use in forming a final product plastic which is a copolymer. Copolymers contain two different alternating chemical entities in the final polymer molecule.
Most commonly a thermosetting resin is used that polymerizes by mixing with a curing agent (polymerization catalyst) at room temperature and normal pressure. The resins are named by analogy with plant resins, but are synthetic monomers for making polymer plastics. The so-called synthetic resins used include polystyrene resin, polyurethane resin, epoxy resin, unsaturated polyester resin, acrylic resin and silicone resin.