Pararealgar
| Pararealgar | |
|---|---|
 |
|
| General | |
| Category | Sulfide mineral |
|
Formula (repeating unit) |
As4S4 |
| Strunz classification | 2.FA.15b |
| Crystal system | Monoclinic |
| Crystal class | Prismatic (2/m) (same H-M symbol) |
| Space group | P21/c |
| Unit cell | a = 9.909 Å, b = 9.655 Å, c = 8.502 Å; β = 97.20°; Z = 16 |
| Identification | |
| Colour | Bright yellow when powdery, to yellow-orange and orange-brown when granular |
| Crystal habit | Fine powder to granular |
| Fracture | Uneven |
| Tenacity | Brittle |
| Mohs scale hardness | 1 – 1.5 |
| Lustre | Vitreous to resinous |
| Streak | Bright yellow |
| Diaphaneity | Translucent |
| Specific gravity | 3.52 |
| Optical properties | Biaxial (?) |
| Birefringence | 2.02 |
| Pleochroism | High: x = orange yellow, y = bright yellow, z = orange red |
| References | |
Pararealgar is an arsenic sulfide mineral with the chemical formula As4S4 also represented as AsS. It forms gradually from realgar under exposure to light. Its name derives from the fact that its elemental composition is identical to realgar, As4S4. It is soft with a Mohs hardness of 1 - 1.5, is yellow orange in colour, and its monoclinic prismatic crystals are very brittle, easily crumbling to powder.
It is one of the sulfides of arsenic and is one of two isomers of As4S4. It forms upon exposure of the symmetrical isomer to light. Its name derives from the fact that its elemental composition is identical to realgar, As4S4.
Both isomers of As4S4 are molecular, in contrast to the other main sulfide of arsenic, orpiment (As2S3), which is polymeric. In pararealgar, there are three kinds of As centres (and three kinds of S centres). The molecule has Cssymmetry. In realgar, the four As (and four S) centres are equivalent and the molecule has D2d symmetry. An analogous pair of isomers is also recognized for the corresponding phosphorus sulfides P4S4.
Pararealgar occurs as an alteration product of realgar in stibnite-bearing quartz veins typically as a result of exposure to light. It occurs associated with realgar, stibnite, tetrahedrite, arsenopyrite, duranusite, native arsenic, arsenolite, native sulfur, lepidocrocite and pyrite.
...
Wikipedia