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P-p chain


The proton–proton chain reaction is one of the two (known) sets of fusion reactions by which stars convert hydrogen to helium. It dominates in stars the size of the Sun or smaller. (The other reaction is the CNO cycle, a catalytic cycle, which theoretical models suggest is the dominant source of energy in stars more massive than about 1.3 times the mass of the Sun.)

In general, proton–proton fusion can occur only if the kinetic energy (i.e. temperature) of the protons is high enough to overcome their mutual electrostatic or Coulomb repulsion.

In the Sun, deuterium-producing events are rare. Diprotons are the much more common result of proton–proton reactions within the star, and diprotons almost immediately decay back into two protons. Since the conversion of hydrogen to helium is slow, the complete conversion of the hydrogen in the core of the Sun is calculated to take more than ten billion years.

The theory that proton–proton reactions are the basic principle by which the Sun and other stars burn was advocated by Arthur Eddington in the 1920s. At the time, the temperature of the Sun was considered to be too low to overcome the Coulomb barrier. After the development of quantum mechanics, it was discovered that tunneling of the wavefunctions of the protons through the repulsive barrier allows for fusion at a lower temperature than the classical prediction.

Even so, it was unclear how proton–proton fusion might proceed, because the most obvious product, helium-2 (diproton), is unstable and almost instantly dissociates back into two protons. In 1939, Hans Bethe proposed that one of the protons could decay by beta emission into a neutron via the weak interaction during the brief moment of fusion, making deuterium a vital product in the chain. This idea was part of the body of work in stellar nucleosynthesis for which Bethe won the Nobel Prize in Physics in 1967.


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