Oil bubbler

A gas bubbler is a piece of laboratory glassware which consists of a glass bulb filled with a small amount of fluid — usually mineral or silicone oil, less commonly mercury. The inlet to the bulb is connected to a ground glass joint, while the outlet is vented to the air.

Gas bubblers are used to exclude air from a reaction or a system. In the former case, the gas bubbler is fitted on the condenser of the reaction set-up. In the latter case, an oil bubbler is usually installed at the end of the inert gas manifold on a Schlenk line to prevent contamination by atmospheric oxygen and water.

A gas bubbler acts as a one-way valve — gases (hot air, evolved gases, solvent vapors) from the inlet will bubble through the fluid before being vented to the atmosphere. If there were an underpressure in the reaction vessel (such as when heat is removed, and the gases within contract), some fluid is sucked into a sump to equalize the pressure, instead of air. Wherever possible, such "suck back" should be avoided by filling the reaction apparatus with inert gas because an excessively low pressure will cause oil to be sucked into the reaction vessel, contaminating it.

The bubbles allow the worker to visibly confirm that the system is being flushed with inert gas; the rate at which bubbles form allow the worker to adjust the inlet pressure.

Oil bubblers are filled with mineral or silicone oil. These are both quite resistant to chemical attack. Oil bubblers are predominantly used; the oil is inexpensive and not toxic.

A drawback is that due to oil's lower density, in event of underpressure in the reaction vessel, enough oil may be sucked through the sump into the inert gas system to contaminate it. Due to the same reason, the pressure within the inert gas system will always remain close to atmospheric. This is a disadvantage when attempting cannula transfers using inert gas pressure to force a liquid reagent into another using a cannula.

Mercury bubblers are largely similar in construction to oil bubblers. They usually have a longer body to prevent mercury from splashing out through the bubbler outlet, and the inlet connection usually has a sintered glass disc to prevent mercury from being sucked back into the inert gas system when refilling an evacuated vessel.

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Wikipedia