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Nuclides


A nuclide (from nucleus) is an atomic species characterized by the specific constitution of its nucleus, i.e., by its number of protons Z, its number of neutrons N, and its nuclear energy state.

The word nuclide was proposed by Truman P. Kohman in 1947. Kohman originally suggested nuclide as referring to a "species of nucleus" defined by containing a certain number of neutrons and protons. The word thus was originally intended to focus on the nucleus.

Nuclide refers to a nucleus rather than to an atom. Identical nuclei belong to one nuclide, for example each nucleus of the carbon-13 nuclide is composed of 6 protons and 7 neutrons. The nuclide concept (referring to individual nuclear species) emphasizes nuclear properties over chemical properties, while the isotope concept (grouping all atoms of each element) emphasizes chemical over nuclear. The neutron number has large effects on nuclear properties, but its effect on chemical properties is negligible for most elements. Even in the case of the very lightest elements where the ratio of neutron number to atomic number varies the most between isotopes it usually has only a small effect, although it does matter in some circumstances (for hydrogen, the lightest element, the isotope effect is large enough to strongly affect biology). Since isotope is the older term, it is better known than nuclide, and is still sometimes used in contexts where nuclide might be more appropriate, such as nuclear technology and nuclear medicine.

A set of nuclides with equal proton number (atomic number), i.e., of the same chemical element but different neutron numbers, are called isotopes of the element. Particular nuclides are still often loosely called "isotopes", but the term "nuclide" is the correct one in general (i.e., when Z is not fixed). In similar manner, a set of nuclides with equal mass number A, but different atomic number, are called isobars (isobar = equal in weight), and isotones are nuclides of equal neutron number but different proton numbers. The name isotone has been derived from the name isotope to emphasize that in the first group of nuclides it is the number of neutrons (n) that is constant, whereas in the second the number of protons (p).


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