Noryl
The NORYL family of modified PPE resins consists of amorphous blends of PPO polyphenylene ether (PPE) resin and polystyrene. They combine the inherent benefits of PPE resin (affordable high heat resistance, good electrical insulation properties, excellent hydrolytic stability and the ability to use non-halogen fire retardant packages), with excellent dimensional stability, good processibility and low density.
Originally developed in 1966 by General Electric Plastics (now owned by SABIC). NORYL is a registered trademark of SABIC Innovative Plastics IP B.V.
NORYL resins are a rare example of a homogeneous mixture of two polymers. Most polymers are incompatible with one another, so tend to produce separate phases when mixed. The two polymers compatibility in NORYL resins is due to the presence of a benzene ring in the repeat units of both chains.
The addition of polystyrene to PPE increases the glass transition temperature above 100 °C, owing to the high Tg of PPE, so NORYL resin is stable in boiling water. The precise value of the transition depends on the exact composition of the grade used. There is a smooth linear relation between weight content of polystyrene and the Tg of the blend. Due to its good electrical resistance, it is widely used in switch boxes. However, product design is important in maximising the strength of the product, especially in eliminating sharp corners and other stress concentrations. Injection molding must ensure that moldings are stress-free.
Like most other amorphous thermoplastics, Noryl is sensitive to environmental stress cracking when in contact with many organic liquids. Compounds such as gasoline, kerosene, and methylene chloride may initiate brittle cracks resulting in product failure.
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