In atmospheric chemistry, NOx is a generic term for the nitrogen oxides that are most relevant for air pollution, namely nitric oxide (NO) and nitrogen dioxide (NO2). These gases contribute to the formation of smog and acid rain, as well as tropospheric ozone.
NOx gases are usually produced from the reaction among nitrogen and oxygen during combustion of fuels, such as hydrocarbons, in air; especially at high temperatures, such as occur in car engines. In areas of high motor vehicle traffic, such as in large cities, the nitrogen oxides emitted can be a significant source of air pollution. NOx gases are also produced naturally by lightning.
The term NOx is chemistry shorthand for molecules containing one nitrogen and one or more oxygen atom. It is generally meant to include nitrous oxide (N2O), a fairly inert oxide of nitrogen that has many uses as an oxidizer for rockets and car engines, an anesthetic, and a propellant for aerosol sprays and whipped cream. Nitrous oxide plays hardly any role in air pollution, although it may have a significant impact on the ozone layer, and is a significant greenhouse gas.
NOy (reactive, free radical) is defined as the sum of NOx plus the NOz compounds produced from the oxidation of NOx which include nitric acid.