Methane cycle
Atmospheric methane is the methane present in Earth's atmosphere. Atmospheric methane concentrations are of interest because it is one of the most potent greenhouse gases in Earth's atmosphere. The 100-year global warming potential of methane is 28. That is, over a 100-year period, it traps 28 times more heat per mass unit than carbon dioxide and 32 times the effect when accounted for aerosol interactions. Global methane levels, had risen to 1800 parts per billion (ppb) by 2011, an increase by a factor of 2.5 since pre-industrial times, from 722 ppb, the highest value in at least 800,000 years. Its concentration is higher in the Northern Hemisphere since most sources (both natural and human) are located on land and the Northern Hemisphere has more land mass. The concentrations vary seasonally, with, for example, a minimum in the northern tropics during April−May mainly due to removal by the hydroxyl radical.
Early in the Earth's history carbon dioxide and methane likely produced a greenhouse effect. The carbon dioxide would have been produced by volcanoes and the methane by early microbes. During this time, Earth's earliest life appeared. These first, ancient bacteria added to the methane concentration by converting hydrogen and carbon dioxide into methane and water. Oxygen did not become a major part of the atmosphere until photosynthetic organisms evolved later in Earth's history. With no oxygen, methane stayed in the atmosphere longer and at higher concentrations than it does today.
Methane is created near the surface, and it is carried into the stratosphere by rising air in the tropics. Uncontrolled build-up of methane in Earth's atmosphere is naturally checked—although human influence can upset this natural regulation—by methane's reaction with hydroxyl radicals formed from singlet oxygen atoms and with water vapor.
Methane in the Earth's atmosphere is a strong greenhouse gas with a global warming potential of 28 over a 100-year period. This means that a methane emission will have 28 times the impact on temperature of a carbon dioxide emission of the same mass over the following 100 years. Methane has a large effect (24 times as strong as carbon dioxide per unit mole) for a brief period (having an estimated lifetime of 8.9±0.6 years in the atmosphere), whereas carbon dioxide has a small effect for a long period (over 100 years). Because of this difference in effect and time period, the global warming potential of methane over a 20-year time period is 72.
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