Mercury batteries

A mercury battery (also called mercuric oxide battery, or mercury cell) is a non-rechargeable electrochemical battery, a primary cell. Mercury batteries use a reaction between mercuric oxide and zinc electrodes in an alkaline electrolyte. The voltage during discharge remains practically constant at 1.35 volts, and the capacity is much greater than a similarly sized zinc carbon battery. Mercury batteries were used in the shape of button cells for watches, hearing aids, cameras and calculators, and in larger forms for other applications.

For a time during and after World War II, batteries made with mercury became a popular power source for portable electronic devices. Due to the content of toxic mercury and environmental concerns about its disposal, the sale of mercury batteries is now banned in many countries. Both ANSI and IEC have withdrawn their standards for mercury batteries.

The mercury oxide-zinc battery system was known more than 100 years ago but did not become widely used until 1942, when Samuel Ruben developed a balanced mercury cell which was useful for military applications such as metal detectors, munitions, and walkie-talkies. The battery system had the advantages of long shelf life (to 10 years) and steady voltage output. After the Second World War the battery system was widely applied for small electronic devices such as cardiac pacemakers and hearing aids. Mercury oxide batteries were made in a range of sizes from miniature button cells used for hearing aids and electric wrist watches, cylindrical types used for portable electronic apparatus, rectangular batteries used for transistor radios, and large multicell packs used for industrial applications such as radio remote control for overhead crane systems. In the United States, mercury oxide batteries were manufactured by companies including P. R. Mallory and Co Inc, (now Duracell), Union Carbide Corporation (whose former battery division is now called Energizer Holdings), RCA Corporation, and Burgess Battery Company.

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