Mercury arc valve

A mercury-arc valve or mercury-vapor rectifier or (UK) mercury-arc rectifier is a type of electrical rectifier used for converting high-voltage or high-current alternating current (AC) into direct current (DC). It is a type of cold cathode gas-filled tube, but is unusual in that the cathode, instead of being solid, is made from a pool of liquid mercury and is therefore self-restoring. As a result, mercury-arc valves were much more rugged and long-lasting, and could carry much higher currents than most other types of gas discharge tube.

Invented in 1902 by Peter Cooper Hewitt, mercury-arc rectifiers were used to provide power for industrial motors, electric railways, streetcars, and electric locomotives, as well as for radio transmitters and for high-voltage direct current (HVDC) power transmission. They were the primary method of high power rectification before the advent of semiconductor rectifiers, such as diodes, thyristors and gate turn-off thyristors (GTOs) in the 1970s. These solid state rectifiers have since completely replaced mercury-arc rectifiers thanks to their higher reliability, lower cost and maintenance and lower environmental risk.

In 1882 Jemin and Meneuvrier observed the rectifying properties of a mercury arc. The mercury arc rectifier was invented by Peter Cooper Hewitt in 1902 and further developed throughout the 1920s and 1930s by researchers in both Europe and North America. Before its invention, the only way to convert AC current provided by utilities to DC was by using expensive, inefficient, and high-maintenance rotary converters or motor-generator sets. Mercury-arc rectifiers or "converters" were used for charging storage batteries, arc lighting systems, the DC traction motors for trolleybuses, trams, and subways, and electroplating equipment. The mercury rectifier was used well into the 1970s, when it was finally replaced by semiconductor rectifiers.

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