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Melilite

Melilite
Orthit 12.jpg
Orthite and melilite (blue) with quartz, from a thin section in crossed polarized light.
General
Category Sorosilicates
Formula
(repeating unit)
(Ca,Na)2(Al,Mg,Fe2+)[(Al,Si)SiO7]
Strunz classification 9.BB.**
Crystal system Tetragonal
Identification
Color Yellowish, greenish brown
Crystal habit Massive - granular
Cleavage Distinct on {001}, weak on {110}
Fracture Uneven
Mohs scale hardness 5 - 5.5
Luster Vitreous - greasy
Streak white
Diaphaneity Translucent
Specific gravity 2.9- 3.0
Optical properties Uniaxial (-)
Refractive index nω = 1.632 - 1.669 nε = 1.626 - 1.658
Birefringence δ = 0.006 - 0.011
References

Melilite refers to a mineral of the melilite group. Minerals of the group are solid solutions of several endmembers, the most important of which are gehlenite and åkermanite. A generalized formula for common melilite is (Ca,Na)2(Al,Mg,Fe2+)[(Al,Si)SiO7]. Discovered in 1793 near Rome, it has a yellowish, greenish-brown color. The name derives from the Greek words meli (μέλι) "honey" and lithos (λίθους) "stone".

Minerals of the melilite group are sorosilicates. They have the same basic structure, of general formula A2B(T2O7). The melilite structure consist of pairs of fused TO4, where T may be Si, Al, B, in bow-tie form. Sharing one corner, the formula of the pair is T2O7. These bow-ties are linked together into sheets by the B cations. The sheets are held together by the A cations, most commonly calcium and sodium. Aluminium may sit on either the T or the B site.

Minerals with the melilite structure may show a cleavage parallel to the (001) crystallographic directions and may show weaker cleavage perpendicular to this, in the {110} directions. Melilite is tetragonal.

The important endmembers of common melilite are åkermanite Ca2Mg(Si2O7) and gehlenite Ca2Al[AlSiO7]. Many melilites also contain appreciable iron and sodium.


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