Mary was the daughter, sister, wife, and mother of various Viscounts of Béarn, Gabardan, and Brulhois. Briefly, from 1170 to 1171, she ruled Béarn as Viscountess in her own right
Mary was the only known daughter of Peter II and Matelle de Baux. When Mary's elder brother Gaston V died without descendants, she inherited his titles. This title was rarely carried by women and Mary was only the second to use the title for herself, but only briefly, until she married.
Her only known act during her brief reign was the act of homage rendered at Jaca to Alfonso II of Aragon on 30 April 1170. Mary and a delegation of Bearnese nobles accepted an oath containing several newly inserted clauses of Alfonso's making which asserted the Crown of Aragon's absolute rights and total control over and above the three viscounties of Béarn, Gabardan, and Brulhois. Alfonso thus usurped the rights of the Duke of Aquitaine, which had long before gone dormant. He also reserved the right to choose Mary's future husband and thus bestow Béarn on whomever he pleased.
In March 1171, the Catalan William of Montcada did homage to Alfonso for Béarn, implicitly as Mary's husband. Mary does not thenceforth reappear with the vicecomital title. However, the Catalan was not acceptable to the Bearnese nobless, who promptly rebelled against their new liege lord. Immediately they elected Theobald of the neighboring County of Bigorre as their viscount, but, as he did not respect the Fors de Bearn, they executed him within the year. They then selected a nobleman of the Auvergne, Sentonge, who lasted two years in power before suffering the same sad fate at the hands of the nobles. Throughout this whole period, William planned to conquer Béarn, but never got around to actually launching any military expedition.