Ligand-field splitting parameter
A spectrochemical series is a list of ligands ordered on ligand strength and a list of metal ions based on oxidation number, group and its identity. In crystal field theory, ligands modify the difference in energy between the d orbitals (Δ) called the ligand-field splitting parameter for ligands or the crystal-field splitting parameter, which is mainly reflected in differences in color of similar metal-ligand complexes.
The spectrochemical series was first proposed in 1938 based on the results of absorption spectra of cobalt complexes.
A partial spectrochemical series listing of ligands from small Δ to large Δ is given below. (for a table, see the ligand page)
O22−< I− < Br− < S2− < SCN− (S–bonded) < Cl− < N3− < F−< NCO− < OH− < C2O42− ≈ H2O < NCS− (N–bonded) < CH3CN < py (pyridine) < NH3 < en (ethylenediamine) < bipy (2,2'-bipyridine) < phen (1,10-phenanthroline) < NO2− < PPh3 < CN− ≈ CO
Ligands arranged on the left end of this spectrochemical series are generally regarded as weaker ligands and cannot cause forcible pairing of electrons within 3d level and thus form outer orbital octahedral complexes. On the other hand, ligands lying at the right end are stronger ligands and form inner orbital octahedral complexes after forcible pairing of electrons within 3d level and hence are called low spin ligands.
However, keep in mind that "the spectrochemical series is essentially backwards from what it should be for a reasonable prediction based on the assumptions of crystal field theory." This deviation from crystal field theory highlights the weakness of crystal field theory's assumption of purely ionic bonds between metal and ligand.
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