Libertyville is an unincorporated community in southeastern St. Francois County, in the U.S. state of Missouri. The community is on Missouri Route DD east of Knob Lick and north of Mine La Motte. The village sits at the headwaters of the Little St. Francis River.
A post office called Libertyville was established in 1863, and remained in operation until 1919. The community most likely takes its name from Liberty Township. Variant names were "Kinkead" and "Liberty Meeting House".
Coordinates: 37°42′13″N 90°17′17″W / 37.70361°N 90.28806°W