John F. Hartwig | |
---|---|
Hartwig delivering his 2014 award lecture for the 2014 Nagoya Medal of Organic Chemistry
|
|
Born | John F. Hartwig 1964 (Elmhurst, IL) United States |
Nationality | American |
Fields | Chemistry |
Institutions | University of California, Berkeley |
Alma mater | Ph.D (1990) University of California, Berkeley A.B. (1986) Princeton University |
Doctoral advisors | Robert G. Bergman and Richard A. Anderson |
Known for | Organometallic chemistry, inorganic chemistry, Catalysis |
Notable awards | Willard Gibbs Award (2015) |
John F. Hartwig is the Henry Rapoport Professor of Chemistry at the University of California, Berkeley. His laboratory focuses on developing new methods for the preparation of a broad range of organic compounds. His explorations have illustrated the potential of the transition metal-catalyzed construction of important carbon-carbon and carbon-heteroatom linkages in a way that has elevated such transformations to strategy level reactions.
Hartwig is known for helping develop the Buchwald–Hartwig amination, a chemical reaction used in organic chemistry for the synthesis of carbon–nitrogen bonds via the palladium-catalyzed cross-coupling of amines with aryl halides. Here is an example of this reaction:
He also helped develop a technique for steric-directed C–H borylation of arenes. The versatility of this method is described in the following reaction scheme:
Hartwig received his A.B. from Princeton University in 1986, and earned his Ph.D. in Chemistry from the University of California, Berkeley in 1990.