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Iron oxychloride

Iron oxychloride
Names
IUPAC name
Iron oxychloride
Identifiers
3D model (Jmol)
ChemSpider
ECHA InfoCard 100.054.740
EC Number 260-233-0
PubChem CID
Properties
ClFeO
Molar mass 107.29 g·mol−1
Appearance Vivid, dark violet, opaque crystals
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N  (what is YesYN ?)
Infobox references

Iron oxychloride is the inorganic compound with the formula FeOCl. This purple solid adopts a layered structure, akin to that of cadmium chloride. The material slowly hydrolyses in moist air. The solid intercalates electron-donors such as tetrathiafulvalene and even pyridine to give mixed valence charge-transfer salts. Intercalation is accompanied by a marked increase in electrical conductivity and a color change to black.

FeOCl is prepared by heating iron(III) oxide with ferric chloride at 370 °C over the course of several days:



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