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Iridium tetroxide

Iridium(VIII) oxide
Ruthenium-tetroxide-3D-balls.png
Names
IUPAC name
Iridium(VIII) oxide
Identifiers
Properties
IrO4
Molar mass 256.215 g/mol
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Iridium tetroxide (IrO4, Iridium(VIII) oxide) is a binary compound of oxygen and iridium in oxidation state +VIII. This compound was formed by photochemical rearrangement of [(η1O2)IrO2] in solid argon at a temperature of 6 K (−267 °C, −449 °F). At higher temperatures the oxide is unstable. The detection of the iridium tetroxide cation by infrared photodissociation spectroscopy with formal oxidation state IX has been reported.


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