Ideal gas equation

The ideal gas law is the equation of state of a hypothetical ideal gas. It is a good approximation of the behavior of many gases under many conditions, although it has several limitations. It was first stated by Émile Clapeyron in 1834 as a combination of the empirical Boyle's law, Charles's law and Avogadro's Law. The ideal gas law is often written as

where:

It can also be derived from the microscopic kinetic theory, as was achieved (apparently independently) by August Krönig in 1856 and Rudolf Clausius in 1857.

The state of an amount of gas is determined by its pressure, volume, and temperature. The modern form of the equation relates these simply in two main forms. The temperature used in the equation of state is an absolute temperature: the appropriate SI unit is the kelvin.

The most frequently introduced form is

where:

In SI units, P is measured in pascals, V is measured in cubic metres, n is measured in moles, and T in kelvins (the Kelvin scale is a shifted Celsius scale, where 0.00 K = −273.15 °C, the lowest possible temperature). R has the value 8.314 J/(K·mol) ≈ 2 cal/(K·mol), or 0.08206 L·atm/(mol·K).

How much gas is present could be specified by giving the mass instead of the chemical amount of gas. Therefore, an alternative form of the ideal gas law may be useful. The chemical amount (n) (in moles) is equal to the total mass of the gas (m) (in grams) divided by the molar mass (M) (in grams per mole):

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