The hardenability of a metal alloy is the depth up to which a material is hardened after putting through a heat treatment process.The unit of hardenability is the same as of length. It is an indication of how deep into the material a certain hardness can be achieved. It should not be confused with hardness, which is a measure of a sample's resistance to indentation or scratching. It is an important property for welding, since it is inversely proportional to weldability, that is, the ease of welding a material.
When a steel work-piece is quenched, the area in contact with the water immediately cools and evens out with that of the medium. The inner depths of the material however, do not cool quite so rapidly and in work-pieces that are large, the cooling rate may be slow enough to allow the austenite to transform fully into a structure other than martensite or bainite. This results in a work-piece that does not have the same crystal structure throughout its entire structure; with a softer core and harder "shell". The softer core is some combination of ferrite and cementite, such as pearlite.
The hardenability of ferrous alloys, i.e. steels, is a function of the carbon content and other alloying elements and the grain size of the austenite. The relative importance of the various alloying elements is calculated by finding the equivalent carbon content of the material. The fluid used for quenching the material influences the cooling rate due to varying thermal conductivities and specific heats. Substances like brine and water cool much more quickly than oil or air. Additionally, if the fluid is agitated cooling occurs even more quickly. The geometry of the part also affects the cooling rate: of two samples of equal volume, the one with higher surface area will cool faster.