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Hübnerite

Hubnerite
Hubnerite-177944.jpg
Hubnerite from Silverton District, San Juan County, Colorado (Size: 8.5 x 6.6 x 4.3 cm)
General
Category Oxide minerals
Formula
(repeating unit)
MnWO4
Strunz classification 4.DB.30
Crystal system Monoclinic
Crystal class Prismatic (2/m)
(same H-M symbol)
Space group P21/c
Unit cell a = 4.86, b = 5.78
c = 5.02 [Å]; β = 90.816°, Z = 4
Identification
Color Yellowish brown to reddish brown, blackish brown, black; Deep red internal reflections in reflected light
Crystal habit Prismatic striated crystals, tabular to flattened, in radiating groups
Twinning Contact twins
Cleavage Perfect on {010}
Fracture Irregular/uneven
Tenacity Brittle
Mohs scale hardness 4-4½
Luster Metallic to adamantine towards resinous.
Streak Yellow to reddish brown, greenish gray
Diaphaneity Transparent to translucent
Specific gravity 7.12 - 7.18
Optical properties Biaxial (+)
Refractive index nα=2.17-2.2, nβ=2.22, nγ=2.3-2.32
Birefringence 0.1200-0.1300
Pleochroism Perceptible; X = yellow to green, red-orange; Y = yellowish brown to greenish yellow, red-orange to red; Z = green; brick-red to red
2V angle 73° measured
References

Hübnerite or hubnerite is a mineral consisting of manganese tungsten oxide (chemical formula: MnWO4, it isn't a tungstate). It is the manganese endmember of the manganese - iron wolframite solid solution series. It forms reddish brown to black monoclinic prismatic submetallic crystals. The crystals are typically flattened and occur with fine striations. It has a high specific gravity of 7.15 and a Mohs hardness of 4.5. It is transparent to translucent with perfect cleavage. Refractive index values are nα=2.170 - 2.200, nβ=2.220, and nγ=2.300 - 2.320.

Typical occurrence is in association with high-temperature hydrothermal vein deposits and altered granites with greisen, granite pegmatites and in alluvial deposits. It occurs associated with cassiterite, arsenopyrite, molybdenite, tourmaline, topaz, rhodochrosite and fluorite.

It was first described in 1865 for an occurrence in the Erie and Enterprise veins, Mammoth district, Nye County, Nevada, and named after the German mining engineer and metallurgist, Adolf Hübner from Freiberg, Saxony.


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