Gas pycnometer
A gas pycnometer is a laboratory device used for measuring the density—or, more accurately, the volume—of solids, be they regularly shaped, porous or non-porous, monolithic, powdered, granular or in some way comminuted, employing some method of gas displacement and the volume:pressure relationship known as Boyle's Law. A gas pycnometer is also sometimes referred to as a helium pycnometer.
Gas expansion pycnometer is also known as constant volume gas pycnometer. The simplest type of gas pycnometer (due to its relative lack of moving parts) consists of two chambers, one (with a removable gas-tight lid) to hold the sample and a second chamber of fixed, known (via calibration) internal volume – referred to as the reference volume or added volume. The device additionally comprises a valve to admit a gas under pressure to one of the chambers, a pressure measuring device – usually a transducer – connected to the first chamber, a valved pathway connecting the two chambers, and a valved vent from the second of the chambers. In practice the sample may occupy either chamber, that is gas pycnometers can be constructed such that the sample chamber is pressurized first, or such that it is the reference chamber that starts at the higher pressure. Various design parameters have been analyzed by Tamari. The working equation of a gas pycnometer wherein the sample chamber is pressurized first is as follows:
where Vs is the sample volume, Vc is the volume of the empty sample chamber (known from a prior calibration step), Vr is the volume of the reference volume (again known from a prior calibration step), P1 is the first pressure (i.e. in the sample chamber only) and P2 is the second (lower) pressure after expansion of the gas into the combined volumes of sample chamber and reference chamber.
Derivation of the "working equation" and a schematic illustration of such a gas expansion pycnometer is given by Lowell et al..
Variable volume pycnometer (or gas comparison pycnometer) consists of either a single or two variable volume chambers. The sample cell volume can be at different types and size, like G-DenPyc 2900 technology specified, the volume can be 0.1ml up to 500ml. The volume of the chamber(s) can be varied by either a fixed amount by a simple mechanical piston of fixed travel, or continuously and gradually by means of a graduated piston. Resulting changes in pressure can be read by means of a transducer, or nullified by adjustment of a third ancillary, graduated variable-volume chamber. This type of pycnometer is commercially obsolete; in 2006 ASTM withdrew its standard test method D2856 for the open-cell content of rigid cellular plastics by the air pycnometer, which relied upon the use of a variable volume pycnometer, and was replaced by test method D6226 which describes a gas expansion pycnometer.
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