The free surface effect is a mechanism which can cause a watercraft to become unstable and capsize.
It refers to the tendency of liquids — and of unbound aggregates of small solid objects, like seeds, gravel, or crushed ore, whose behavior approximates that of liquids — to move in response to changes in the attitude of a craft's cargo holds, decks, or liquid tanks in reaction to operator-induced motions (or sea states caused by waves and wind acting upon the craft). When referring to the free surface effect, the condition of a tank that is not full is described as a "slack tank", while a full tank is "pressed up".
In a normally laden vessel any rolling from perpendicular is countered by a righting moment generated from the increased volume of water displaced by the hull on the lowered side. This assumes the center of gravity of the vessel is relatively constant. If a moving mass inside the vessel moves in the direction of the roll, this counters the righting effect by moving the center of gravity towards the lowered side. The free surface effect can become a problem in a craft with large partially full bulk cargo compartments, fuel tanks, or water tanks (especially if they span the full breadth of the ship), or from accidental flooding, such as has occurred in several accidents involving roll-on/roll-off ferries.
If a compartment or tank is either empty or full, there is no change in the craft's center of mass as it rolls from side to side (in strong winds, heavy seas, or on sharp motions or turns). However, if the compartment is only partially full, the liquid in the compartment will respond to the vessel's heave, pitch, roll, surge, sway or yaw. For example, as a vessel rolls to port, liquid will displace to the port side of a compartment, and this will move the vessel's center of mass to port. This has the effect of slowing the vessel's return to vertical.
The momentum of large volumes of moving liquids cause significant dynamic forces, which act against the righting effect. When the vessel returns to vertical the roll continues and the effect is repeated on the opposite side. In heavy sea states, this can become a positive feedback loop, causing each roll to become more and more extreme, eventually overcoming the righting effect leading to a capsize. While repeated oscillations of increasing magnitude are commonly associated with the free surface effect, they are not a necessary condition. For example, in the cases of both the SS Normandie and MS al-Salam Boccaccio 98, gradual buildup of water from fire-fighting caused capsizing in a single continuous roll.