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Florencite

Florencite-(Sm)
General
Category Phosphate mineral
Formula
(repeating unit)
SmAl3(PO4)2(OH)6
Crystal system Trigonal
Crystal class Hexagonal scalenohedral (3m)
H-M symbol: (3 2/m)
Space group R3m
Unit cell a = 6.972, c = 16.182 [Å]; Z = 3
Identification
Color Colorless, pale pink, pale yellow
Crystal habit Sub-mm zones in florencite-(Ce) crystals
Cleavage {0001}, distinct
Fracture Uneven
Mohs scale hardness 5.5-6
Luster Vitreous to greasy
Streak White
Density 3.6 (measured)
Optical properties Uniaxal(+)
Refractive index nω=1.70, nε=1.71
References "Florencite-(Sm) - Handbook of Mineralogy" (PDF). Handbookofmineralogy.org. 

Florencite-(Sm) is a very rare mineral of the plumbogummite group (alunite supergroup) with simplified formula SmAl3(PO4)2(OH)6. Samarium in florencite-(Sm) is substituted by other rare earth elements, mostly neodymium. It does not form separate crystals, but is found as zones in florencite-(Ce), which is cerium-dominant member of the plumbogummite group. Florencite-(Sm) is also a samarium-analogue of florencite-(La) (lanthanum-dominant) and waylandite (bismuth-dominant), both being aluminium-rich minerals.

Florencite-(Sm) was revealed in quartz veins in the Maldynyrd Range, Subpolar Urals, Russia. It associates with xenotime-(Y).

Florencite-(Sm) has admixtures of neodymium, and small amounts of cerium, gadolinium, sulfur, strontium, praseodymium, calcium, lanthanum, europium, and silicon.



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