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Fermi–Dirac distribution


In quantum statistics, a branch of physics, Fermi–Dirac statistics describe a distribution of particles over energy states in systems consisting of many identical particles that obey the Pauli exclusion principle. It is named after Enrico Fermi and Paul Dirac, each of whom discovered the method independently (although Fermi defined the statistics earlier than Dirac).

Fermi–Dirac (F–D) statistics apply to identical particles with half-integer spin in a system with thermodynamic equilibrium. Additionally, the particles in this system are assumed to have negligible mutual interaction. That allows the many-particle system to be described in terms of single-particle energy states. The result is the F–D distribution of particles over these states which includes the condition that no two particles can occupy the same state; this has a considerable effect on the properties of the system. Since F–D statistics apply to particles with half-integer spin, these particles have come to be called fermions. It is most commonly applied to electrons, which are fermions with spin 1/2. Fermi–Dirac statistics are a part of the more general field of statistical mechanics and use the principles of quantum mechanics.

Before the introduction of Fermi–Dirac statistics in 1926, understanding some aspects of electron behavior were difficult due to seemingly contradictory phenomena. For example, the electronic heat capacity of a metal at room temperature seemed to come from 100 times fewer electrons than were in the electric current. It was also difficult to understand why those emission currents generated by applying high electric fields to metals at room temperature were almost independent of temperature.


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