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Eutectic mixture


A eutectic system (/juːˈtɛktɪk/ yew-TEK-tik) from the Greek "ευ" (eu = easy) and "Τήξις" (teksis = melting) describes a homogeneous solid mix of atomic and/or chemical species, to form a joint super-lattice, by striking a unique atomic percentage ratio between the components — as each pure component has its own distinct bulk lattice arrangement. It is only in this atomic/molecular ratio that the eutectic system melts as a whole, at a specific temperature (the eutectic temperature) the super-lattice releasing at once all its components into a liquid mixture. The eutectic temperature is the lowest possible melting temperature over all of the mixing ratios for the involved component species.

Upon heating any other mixture ratio, and reaching the eutectic temperature — see the phase diagram to the right — one component's lattice will melt first, while the temperature of the mixture has to further increase for (all) the other component lattice(s) to melt. Conversely, as a non-eutectic mixture cools down, each mixture's component will solidify (form its lattice) at a distinct temperature, until all material is solid.

The coordinates defining a eutectic point on a phase diagram are the eutectic percentage ratio (on the atomic/molecular ratio axis of the diagram) and the eutectic temperature (on the temperature axis of the diagram).

Not all binary alloys have eutectic points because the valence electrons of the component species are not always compatible, in any mixing ratio, to form a new type of joint crystal lattice. For example, in the silver-gold system the melt temperature (liquidus) and freeze temperature (solidus) "meet at the pure element endpoints of the atomic ratio axis while slightly separating in the mixture region of this axis".


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