Energy content

In chemistry, chemical energy is the potential of a chemical substance to undergo a transformation through a chemical reaction to transform other chemical substances. Examples include batteries, food, gasoline, and more. Breaking or making of chemical bonds involves energy, which may be either absorbed or evolved from a chemical system.

Energy that can be released (or absorbed) because of a reaction between a set of chemical substances is equal to the difference between the energy content of the products and the reactants, if the initial and final temperatures are the same. This change in energy can be estimated from the bond energies of the various chemical bonds in the reactants and products. It can also be calculated from ${\displaystyle \Delta {U_{f}^{\circ }}_{\mathrm {reactants} }}$, the internal energy of formation of the reactant molecules, and ${\displaystyle \Delta {U_{f}^{\circ }}_{\mathrm {products} }}$ the internal energy of formation of the product molecules. The internal energy change of a chemical process is equal to the heat exchanged if it is measured under conditions of constant volume and equal initial and final temperature, as in a closed container such as a bomb calorimeter. However, under conditions of constant pressure, as in reactions in vessels open to the atmosphere, the measured heat change is not always equal to the internal energy change, because pressure-volume work also releases or absorbs energy. (The heat change at constant pressure is called the enthalpy change; in this case the enthalpy of reaction, if initial and final temperatures are equal).

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