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Diopside

Diopside
Diopside Aoste.jpg
Diopside - Bellecombe, Châtillon, Aosta Valley, Italy
General
Category Silicate mineral
Formula
(repeating unit)
MgCaSi2O6
Strunz classification 9.DA.15
Crystal system Monoclinic
Crystal class Prismatic (2/m)
(same H-M symbol)
Space group C2/c
Unit cell a = 9.746 Å, b = 8.899 Å
c = 5.251 Å; β = 105.79°; Z = 4
Identification
Color Commonly light to dark green; may be blue, brown, colorless, white, grey
Crystal habit Short prismatic crystals common, may be granular, columnar, massive
Twinning Simple and multiple twins common on {100} and {001}
Cleavage Distinct/good on {110}
Fracture Irregular/uneven, conchoidal
Tenacity Brittle
Mohs scale hardness 5.5 - 6.5
Luster Vitreous to dull
Streak white
Specific gravity 3.278
Optical properties Biaxial (+)
Refractive index nα= 1.663 - 1.699, nβ= 1.671 - 1.705, nγ= 1.693 - 1.728
Birefringence δ = 0.030
2V angle Measured: 58° to 63°
Dispersion Weak to distinct, r>v
Melting point 1391 °C
References

Diopside is a monoclinic pyroxene mineral with composition MgCaSi2O6. It forms complete solid solution series with hedenbergite (FeCaSi2O6) and augite, and partial solid solutions with orthopyroxene and pigeonite. It forms variably colored, but typically dull green crystals in the monoclinic prismatic class. It has two distinct prismatic cleavages at 87 and 93° typical of the pyroxene series. It has a Mohs hardness of six, a Vickers hardness of 7.7 GPa at a load of 0.98 N, and a specific gravity of 3.25 to 3.55. It is transparent to translucent with indices of refraction of nα=1.663–1.699, nβ=1.671–1.705, and nγ=1.693–1.728. The optic angle is 58° to 63°.

Diopside is found in ultramafic (kimberlite and peridotite) igneous rocks, and diopside-rich augite is common in mafic rocks, such as olivine basalt and andesite. Diopside is also found in a variety of metamorphic rocks, such as in contact metamorphosed skarns developed from high silica dolomites. It is an important mineral in the Earth's mantle and is common in peridotite xenoliths erupted in kimberlite and alkali basalt.


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