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Desiccant


A desiccant is a hygroscopic substance that induces or sustains a state of dryness (desiccation) in its vicinity. Commonly encountered pre-packaged desiccants are solids that absorb water. Desiccants for specialized purposes may be in forms other than solid, and may work through other principles, such as chemical bonding of water molecules. They are commonly encountered in foods to retain crispness. Industrially, desiccants are widely used to control the level of water in gas streams.

Although some desiccants are chemically inert, many are extremely reactive and require specialized handling techniques. The most common desiccant is silica, an otherwise inert, nontoxic, water-insoluble white solid. Tens of thousands of tons are produced annually for this purpose. Other common desiccants include activated charcoal, calcium sulfate (Drierite),calcium chloride, and molecular sieves (typically, zeolites).

One measure of desiccant efficiency is the ratio (or percentage) of water storable in the desiccant relative to the mass of desiccant.

Another measure is the residual relative humidity of the air or other fluid being dried.

The performance of any desiccant varies with temperature and both relative humidity and absolute humidity. To some extent, desiccant performance can be precisely described, but most commonly, the final choice of which desiccant best suits a given situation, how much of it to use, and in what form, is made based on testing and practical experience.

Sometimes a humidity indicator is included in the desiccant to show, by color changes, the degree of water-saturation of the desiccant. One commonly used indicator is cobalt chloride (CoCl2). Anhydrous cobalt chloride is blue. When it bonds with two water molecules, (CoCl2•2H2O), it turns purple. Further hydration results in the pink hexaaquacobalt(II) chloride complex [Co(H2O)6]Cl2.


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