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Cornwallite

Cornwallite
Cornwallite-178955.jpg
Cornwallite in a vug from Pastrana, Murcia, Spain (size: 4.3 x 3.7 x 2.2 cm)
General
Category Arsenate mineral
Formula
(repeating unit)
Cu5(AsO4)2(OH)4
Strunz classification 8.BD.05
Dana classification 41.4.2.2
Crystal system Monoclinic
Crystal class Prismatic (2/m)
(same H-M symbol)
Space group P21/c
Unit cell a = 17.33 Å, b = 5.82 Å,
c = 4.60 Å; β = 92.22°; Z = 2
Identification
Color Verdigis green, blackish-green, emerald-green
Crystal habit Microcrystalline radial fibrous, botryoidal to globular crusts
Cleavage Distinct in one direction
Fracture Conchoidal
Tenacity Brittle
Mohs scale hardness 4.5
Luster Sub-vitreous, resinous, waxy
Streak Apple green
Diaphaneity Translucent to opaque
Specific gravity 4.17
Optical properties Biaxial (+/-)
Refractive index nα = 1.810 - 1.820 nβ = 1.815 - 1.860 nγ = 1.850 - 1.880
Birefringence δ = 0.040 - 0.060
2V angle Measured: 30° to 50°
References

Cornwallite is an uncommon copper arsenate mineral with formula Cu5(AsO4)2(OH)4. It forms a series with the phosphate pseudomalachite and is a dimorph of the triclinic cornubite. It is a green monoclinic mineral which forms as radial to fibrous encrustations.

It was first described in 1846, for an occurrence in Wheal Gorland, St Day United Mines of the St Day District, Cornwall, England. It occurs as secondary mineral in the oxidized zone of copper sulfide deposits. Associated minerals include olivenite, cornubite, arthurite, clinoclase, chalcophyllite, strashimirite, lavendulan, tyrolite, spangolite, austinite, conichalcite, brochantite, azurite and malachite.


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