Cooper pairs

In condensed matter physics, a Cooper pair or BCS pair is a pair of electrons (or other fermions) bound together at low temperatures in a certain manner first described in 1956 by American physicist Leon Cooper. Cooper showed that an arbitrarily small attraction between electrons in a metal can cause a paired state of electrons to have a lower energy than the Fermi energy, which implies that the pair is bound. In conventional superconductors, this attraction is due to the electron–phonon interaction. The Cooper pair state is responsible for superconductivity, as described in the BCS theory developed by John Bardeen, Leon Cooper, and John Schrieffer for which they shared the 1972 Nobel Prize.

Although Cooper pairing is a quantum effect, the reason for the pairing can be seen from a simplified classical explanation. An electron in a metal normally behaves as a free particle. The electron is repelled from other electrons due to their negative charge, but it also attracts the positive ions that make up the rigid lattice of the metal. This attraction distorts the ion lattice, moving the ions slightly toward the electron, increasing the positive charge density of the lattice in the vicinity. This positive charge can attract other electrons. At long distances, this attraction between electrons due to the displaced ions can overcome the electrons' repulsion due to their negative charge, and cause them to pair up. The rigorous quantum mechanical explanation shows that the effect is due to electron–phonon interactions, with the phonon being the collective motion of the positively-charged lattice.

The energy of the pairing interaction is quite weak, of the order of 10⁻³ eV, and thermal energy can easily break the pairs. So only at low temperatures, in metal and other substrates, are a significant number of the electrons in Cooper pairs.

...
Wikipedia