Calibration of radiocarbon dates

Radiocarbon dating measurements produce ages in "radiocarbon years", which must be converted to calendar ages by a process called calibration. Calibration is needed because the atmospheric 14
C/12
C ratio, which is a key element in calculating radiocarbon ages, has not been constant historically. Although Willard Libby, the inventor of radiocarbon dating, had pointed out as early as 1955 the possibility that the 14
C/12
C ratio might have varied over time, it was not until discrepancies began to accumulate between measured ages and known historical dates for artefacts that it became clear that a correction would need to be applied to radiocarbon ages to obtain calendar dates. Radiocarbon years ago may be abbreviated 14
Cya (years ago). A general term used reflecting evidence from any method is Before Present (BP).

To produce a curve that can be used to relate calendar years to radiocarbon years, a sequence of securely dated samples is needed which can be tested to determine their radiocarbon age. The study of tree rings led to the first such sequence: tree rings from individual pieces of wood show characteristic sequences of rings that vary in thickness because of environmental factors such as the amount of rainfall in a given year. These factors affect all trees in an area, so examining tree-ring sequences from old wood allows the identification of overlapping sequences. In this way, an uninterrupted sequence of tree rings can be extended far into the past. The first such published sequence, based on bristlecone pine tree rings, was created in the 1960s by Wesley Ferguson. Hans Suess used this data to publish the first calibration curve for radiocarbon dating in 1967. The curve showed two types of variation from the straight line: a long term fluctuation with a period of about 9,000 years, and a shorter term variation, often referred to as "wiggles", with a period of decades. Suess said he drew the line showing the wiggles by "cosmic schwung" – freehand, in other words. It was unclear for some time whether the wiggles were real or not, but they are now well-established.

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